Since the browser will always want to open one page or another that is not pinned what I can do is a sort of work-around by pinning the one page that I do not want the browser to open as the start page and then assign the page I do want the browser to open by default as the page in the "Home page" value in preferences.
Only problem is if I want to use the alternate start-page (which sits in front of the default start-page) then all of the links from that alternate start page starts opening pages in front of the default start-page eventually sending it off to a place where it's difficult to find -- so I pretty much have the same problem.
So either way the two pages get separated if I use the alternate start-page (in front of the default). At least since the secondary start-page will be used less often this way is better than just leaving the two pages in a normal state.
Not exactly as I envisioned it but will will have to do if no other alternative is found.
So thanks
SpockMan02 for the idea of trying the "pin" tab option[/b]

Not exactly a solution but may have to do (I kind of figured there would not be a way to combine the first two tabs together as I described).